Spider Not

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SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

Product identifier


Chemical Name

Mixture

CAS No.

Mixture

Trade Name

Spider Not

Product code

10-500987

EPA Identification Number(s)

EPA Reg. No. 358-111

Relevant identified uses of the substance or mixture and uses advised against

Identified Use(s)

Pesticidal spray

Uses Advised Against

It is a violation of Federal law to use this product in a manner inconsistent with its labeling.

Company Identification

Spray Products Corporation

P.O. Box 737

Norristown, PA 19404

Telephone

(610) 277-1010

Fax

(610) 277-4390

E-Mail (competent person)

sds@sprayproducts.com

Emergency telephone number


Emergency Phone No.

Transportation Emergency: CHEMTREC 24 hr. 1-800-424-9300 / 1 (703) 527-3887 (Collect calls accepted)

SECTION 2: HAZARDS IDENTIFICATION

Classification of the substance or mixture

OSHA HCS (29 CFR 1910.1200)

Flam. Aerosol 1; Compressed dissolved gas; Asp. Tox. 1; STOT SE 3; Skin Irrit. 2

Label elements

This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non pesticide chemicals. The hazard information required on the pesticide label is reproduced in section 15 of this SDS.

Hazard Symbol

Signal word(s)

DANGER

Hazard Statement(s)

Extremely flammable aerosol.

Contains gas under pressure; may explode if heated.

Causes skin irritation.

May cause drowsiness or dizziness.

Precautionary Statement(s)

Keep away from heat/sparks/open flames/hot surfaces. – No smoking.

Do not spray on an open flame or other ignition source.

Do not pierce or burn, even after use.

Avoid breathing dust/fume/gas/mist/vapours/spray.

Use only outdoors or in a well-ventilated area.

Wash hands and exposed skin after use.

Wear protective gloves/protective clothing/eye protection/face protection.

Protect from sunlight and do not expose to temperatures exceeding 50 ºC/122 ºF.

Other hazards

Contains: Contains: Contains: N-Octyl Bicycoheptane Dicarboximide (CAS No. 52315-07-8, 0.00375%); Esfenvalerate (CAS No. 66230-04-4, 0.00375%); Prallethrin (CAS No. 23031-36-9, 0.00045%); - May produce an allergic reaction in persons already sensitized. Harmful to aquatic life with long lasting effects.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS


Hazardous Ingredient(s)

% wt. *

CAS No.

Hazard classification

Distillates (petroleum), hydrotreated light

95

64742-47-8

Flam. Liq. 3; H227: Combustible liquid.

Skin Irrit. 2; H315: Causes skin irritation.

Asp. Tox. 1; H304: May be fatal if swallowed and enters airways.

STOT SE 3; H336

Aquatic Chronic 3; H412: Harmful to aquatic life with long lasting effects.

Carbon dioxide

4 - 5

124-38-9

Compressed dissolved gas

N-Octyl Bicycoheptane Dicarboximide**

0.00375

52315-07-8

Acute Tox. 4; H302

Acute Tox. 3;H331

Skin Sens. 1; H317

Aquatic Acute 1; H400

Aquatic Chronic 1; H410

Esfenvalerate**

0.00075

66230-04-4

Prallethrin**

0.00045

23031-36-9


Additional Information - ** May produce an allergic reaction in persons already sensitized.

* The exact percentage withheld as a trade secret in accordance with 29 CFR 1910.1200.

SECTION 4: FIRST AID MEASURES


Description of first aid measures


Inhalation

Move person to fresh air. If breathing is laboured, administer oxygen. If symptoms develop, obtain medical attention.

Skin Contact

Wash affected skin with soap and water. If symptoms develop, obtain medical attention. Take off contaminated clothing and wash it before reuse.

Eye Contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention.

Ingestion

Immediately call a POISON CENTER or doctor/physician. Do not induce vomiting. Do not give anything by mouth to an unconscious person.

Most important symptoms and effects, both acute and delayed

Aspiration of droplets may cause pulmonary oedema. May produce an allergic reaction in persons already sensitized.

Indication of any immediate medical attention and special treatment needed

IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

SECTION 5: FIRE-FIGHTING MEASURES

Extinguishing media


-Suitable Extinguishing Media

Extinguish with carbon dioxide, dry chemical, foam or waterspray.

-Unsuitable extinguishing Media

Do not use water jet.

Special hazards arising from the substance or mixture

None anticipated.

Advice for fire-fighters

A self contained breathing apparatus and suitable protective clothing should be worn in fire conditions. Keep containers cool by spraying with water if exposed to fire.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Eliminate sources of ignition. Avoid contact with skin and eyes. Avoid breathing spray. Wear protective gloves/eye protection.

Environmental precautions

Prevent liquid entering sewers, basements and workpits.

Methods and material for containment and cleaning up

Cover spills with inert absorbent material. Transfer to a container for disposal or recovery.

Reference to other sections

None

Additional Information

None

SECTION 7: HANDLING AND STORAGE

Precautions for safe handling

Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Avoid contact with skin and eyes. Avoid breathing spray. Wash hands thoroughly after handling. Use product in a well-ventilated area only.

Conditions for safe storage, including any incompatibilities


-Storage temperature

Keep in a cool, well ventilated place. Protect from sunlight. °F.

-Incompatible materials

This product should be stored away from sources of strong heat or oxidising chemicals. Strong Acids and Alkalis.

Specific end use(s)

Pesticidal spray

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits



SUBSTANCE.

CAS No.

(8hr TWA)

(STEL)

Note

PEL

(OSHA)

TLV (ACGIH)

PEL

(OSHA)

TLV (ACGIH)

Mineral oils / Oil Mist

-----

5 mg/m3

5 mg/m3(I)

-----

-----

(I)Inhalable

Carbon dioxide

124-38-9

5,000 ppm

5,000 ppm

-----

30,000 ppm

#

#Assure minimum oxygen content of work atmosphere.

Recommended monitoring method

NIOSH 6603 (Carbon dioxide); NIOSH 5026 (Oil mist; mineral)

Exposure controls


Appropriate engineering controls

Provide adequate ventilation to ensure that the occupational exposure limit is not exceeded.

Personal protection equipment



Eye/face protection

Not normally required. Do not get in eyes.


Skin protection (Hand protection/ Other)

Wear suitable gloves if prolonged skin contact is likely. Check with protective equipment manufacturer's data.


Respiratory protection

Normally no personal respiratory protection is necessary. In case of insufficient ventilation, wear suitable respiratory equipment. Check with protective equipment manufacturer's data.


Thermal hazards

Not normally required. Use gloves with insulation for thermal protection, when needed.

Environmental Exposure Controls

Avoid release to the environment.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES


Information on basic physical and chemical properties


Appearance

Aerosol spray

Color.

Clear rless

Odor

Petroleum spirit

Odor Threshold (ppm)

Not available

pH (Value)

Not available

Melting Point (°C) / Freezing Point (°C)

Not available

Boiling point/boiling range (°C):

> 200 (> 392 °F)

Flash Point (°C)

60 - 93 (140 - 199 °F)

Evaporation Rate

Not available

Flammability (solid, gas)

Extremely flammable aerosol.

Explosive Limit Ranges

Not applicable

Vapor pressure (Pascal)

Not available

Vapor Density (Air=1)

Not available

Density (g/ml)

Not available

Solubility (Water)

Not available

Solubility (Other)

Not available

Partition Coefficient (n-Octanol/water)

Not available

Auto Ignition Point (°C)

Not available

Decomposition Temperature (°C)

Not available

Kinematic Viscosity (cSt)

< 20.5 @ 40 °C

Explosive properties

Not available

Oxidizing properties

Not available

Other information

Not available

SECTION 10: STABILITY AND REACTIVITY

Reactivity

Stable under normal conditions.

Chemical stability

Stable.

Possibility of hazardous reactions

None anticipated.

Conditions to avoid

Avoid contact with heat and ignition sources.

Incompatible materials

Strong oxidising agents. Strong Acids and Alkalis.

Hazardous decomposition product(s)

Carbon monoxide, Carbon dioxide, Acrid smoke

SECTION 11: TOXICOLOGICAL INFORMATION

Exposure routes: Inhalation, Skin Contact, Eye Contact

Substances in preparations / mixtures


Distillates (petroleum), hydrotreated light (CAS No. 64742-47-8) - By analogy with similar materials:

Acute toxicity (calculated / estimated)

Oral: LD50 >5000 mg/kg-bw

Dermal: LD50 >2000 mg/kg-bw

Inhalation: LC0 ≥5.28 mg/l (Vapour), 4-hr. rat - May cause drowsiness or dizziness.

Irritation/Corrosivity

Causes skin irritation. Repeated exposure may cause skin dryness or cracking.

Sensitisation

It is not a skin sensitiser.

Repeated dose toxicity

Oral: NOEAL 750 mg/kg

Dermal: NOEAL 0.5 ml/kg bw

Inhalation: NOAEL ≥1000 mg/m3

Carcinogenicity

It is unlikely to present a carcinogenic hazard to man.

NTP

IARC

ACGIH

OSHA

NIOSH

No.

No.

No.

No.

No.


Mutagenicity

Not to be expected

Reproductive toxicity

Not to be expected

Other information

Contains: Contains: Contains: N-Octyl Bicycoheptane Dicarboximide (CAS No. 52315-07-8, 0.00375%); Esfenvalerate (CAS No. 66230-04-4, 0.00375%); Prallethrin (CAS No. 23031-36-9, 0.00045%); May produce an allergic reaction in persons already sensitized.

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity


Distillates (petroleum), hydrotreated light (CAS No. 64742-47-8) - By analogy with similar materials:

Short term

LC50 (96 hour): 2.5 mg/L (fish)

EC50 (48 hour): 1.4 mg/L (crustacea)

EC50 (72 hour): 1.3 mg/L (algae)

Long Term

NOEC (28 days): 0.098 mg/L (fish)

LOEC (21 days): 1.2 mg/L (crustacea)

LOEL (72 hour): 1 mg/L (algae)

Persistence and degradability

Not available.

Bioaccumulative potential

Not available.

Mobility in soil

Not available.

Results of PBT and VPVB assessment

Not classified as PBT or vPvB.

Other adverse effects

None known.

Other information

Contains: Contains: N-Octyl Bicycoheptane Dicarboximide (CAS No. 52315-07-8, 0.00375%); Esfenvalerate (CAS No. 66230-04-4, 0.00375%); Prallethrin (CAS No. 23031-36-9, 0.00045%); Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal should be in accordance with local, state or national legislation. Consult an accredited waste disposal contractor or the local authority for advice.

SECTION 14: TRANSPORT INFORMATION


U.S. DOT

Sea transport

(IMDG)

Air transport (ICAO/IATA)

UN number

1950

1950

1950

Proper Shipping Name

Aerosols, flammable

Aerosols, flammable

Aerosols, flammable

Transport hazard class(es)

2.1

2.1

2.1

Packing group

Not applicable

Not applicable

Not applicable

Environmental hazards

None assigned

None assigned

None assigned

Special precautions for user

None assigned

None assigned

None assigned

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable

SECTION 15: REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture:

TSCA (Toxic Substance Control Act) - Inventory Status: All components listed or polymer exempt.

EPA FIFRA Information for SDS Section 15 (Regulatory Information):


This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non pesticide chemicals.


The hazard information required on the pesticide label is reproduced below:


CAUTION: Harmful if swallowed. Avoid prolonged breathing of spray mist or repeated contact with skin. Do not apply to humans, pets or birds. Wash hands Wash thoroughly with soap and water after using. Do not spray near fish or aquariums. Do not use in dairy barns or poultry houses. Avoid contamination of feed, foodstuffs or water sources. Do not spray painted walls, upholstery, lamps, rugs, finished wood or other decorative surfaces.

Extremely flammable. Contents under pressure. Keep away from fire, sparks and heated surfaces. Do not puncture or incinerate container. Expousre to temperatures above 130 °F may cause bursting.

DISPOSAL: Do not reuse container. Wrap container and put in trash collection.

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Designated Hazardous Substances and Reportable Quantities (40 CFR 302.4):


Chemical Name

CAS No.

Typical %wt.

RQ (Pounds)


None

----

----

----

SARA 311/312 - Hazard Categories:


Fire Sudden Release Reactivity Immediate (acute) Chronic (delayed)

SARA 313 - Toxic Chemicals (40 CFR 372):

Chemical Name

CAS No.

Typical %wt.

None

----

----

SARA 302 - Extremely Hazardous Substances(40 CFR 355):


Chemical Name

CAS No.

Typical %wt.

TPQ (pounds)


None

----

----

----

California Proposition 65 List:


Chemical Name

CAS No.

Type of Toxicity


None

----

----

SECTION 16: OTHER INFORMATION

The following sections contain revisions or new statements: 1-16.

Date of preparation: January 5, 2017

Hazard Statement(s) and Risk Phrases Listed in: SECTION 2:/ SECTION 3:

Hazard Statement(s)

- H227: Combustible liquid.

- H302: Harmful if swallowed.

- H304: May be fatal if swallowed and enters airways.

- H315: Causes skin irritation.

- H317: May cause an allergic skin reaction.

- H331: Toxic if inhaled.

- H336: May cause drowsiness or dizziness.

- H400: Very toxic to aquatic life.

- H410: Very toxic to aquatic life with long lasting effects.

- H412: Harmful to aquatic life with long lasting effects.


Training advice: None.

Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for the user’s own particular use.

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